91̽»¨

Abstract:

Nanostructured materials, including plasmonic metamaterials made from gold and silver nanoparticles, provide access to new materials properties. The assembly of nanoparticles into extended arrays can be controlled through surface functionalization and the use of increasingly sophisticated linkers. We present a versatile way to control the bonding symmetry of gold nanoparticles by wrapping them in flower-shaped DNA origami structures. These ‘nanoflowers’ assemble into two-dimensonal gold nanoparticle lattices with symmetries that can be controlled through auxiliary DNA linker strands. Nanoflower lattices are true composites: interactions between the gold nanoparticles are mediated entirely by DNA, and the DNA origami will only fold into its designed form in the presence of the gold nanoparticles.

Abstract:

We report quantum interference effects in the electrical conductance of chemical vapour deposited graphene nanoconstrictions fabricated using feedback controlled electroburning. The observed multi-mode Fabry-Pérot interferences can be attributed to reflections on potential steps inside the channel. Sharp anti-resonance features with a Fano line shape are observed. Theoretical modelling reveals that these Fano resonances are due to localised states inside the constriction, which couple to the delocalised states that also give rise to the Fabry-Pérot interference patterns. This study provides new insight into the interplay between two fundamental forms of quantum interference in graphene nanoconstrictions.