91̽»¨

Abstract:

We study the effect of electrostatic interactions on the distribution function of the end-to-end distance of a single polyelectrolyte chain in the rod-like limit. The extent to which the radial distribution function of a polyelectrolyte is reproduced by that of a wormlike chain with an adjusted effective persistence length is investigated. Strong evidence is found for a universal scaling formula connecting the effective persistence length of a polyelectrolyte with the strength of the electrostatic interaction and the Debye screening length.

Abstract:

We study the geometry dependence of the Casimir energy for deformed metal plates by a path integral quantization of the electromagnetic field. For the first time, we give a complete analytical result for the deformation induced change in Casimir energy delta E in an experimentally testable, nontrivial geometry, consisting of a flat and a corrugated plate. Our results show an interesting crossover for delta E as a function of the ratio of the mean plate distance H, to the corrugation length lambda: For lambda<>H.

Abstract:

The dynamics of the deformations of a moving contact line was analyzed using two different dissipation mechanism. The contact lines relax to their equilibrium from a distorted configuration with a characteristic inverse decay time because of their anomalous elasticity. It is found that the velocity of the contact lines depends on the dissipation mechanism of the system.

Abstract:

The dynamics of the deformations of a moving contact line is studied assuming two different dissipation mechanisms. It is shown that the characteristic relaxation time for a deformation of wavelength 2pi/|k| of a contact line moving with velocity v is given as tau(-1)(k)=c(v)|k|. The velocity dependence of c(v) is shown to depend drastically on the dissipation mechanism: we find c(v)=c(v=0)-2v for the case in which the dynamics is governed by microscopic jumps of single molecules at the tip (Blake mechanism), and c(v) approximately c(v=0)-4v when viscous hydrodynamic losses inside the moving liquid wedge dominate (de Gennes mechanism). We thus suggest that the debated dominant dissipation mechanism can be experimentally determined using relaxation measurements similar to the Ondarcuhu-Veyssie experiment [T. Ondarcuhu and M. Veyssie, Nature 352, 418 (1991)].