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Abstract:

Solution processable metallic nanomaterials present a convenient way to fabricate conductive structures, which are necessary in all electronic devices. However, they tend to require post-treatments to remove the bulky ligands around them to achieve high conductivity. In this work, we present a method to formulate a post-treatment free conductive silver nanowire ink by controlling the type of ligands around the silver nanowires. We found that bidentate ligands with a rigid molecular structure were effective in improving the conductivity of the silver nanowire networks as they could maximize the number of linkages between neighboring nanowires. In addition, DFT calculations also revealed that ligands with good LUMO to silver energy alignment were more effective. Because of these reasons, fumaric acid was found to be the most effective ligand and achieved a large reduction in sheet resistance of 70% or higher depending on the nanowire network density. The concepts elucidated from this study would also be applicable to other solution processable nanomaterials systems such as quantum dots for photovoltaics or LEDs which also require good charge transport being neighboring nanoparticles.

Abstract:

This data set corresponds to the generated data for the publication entitled with the same name to appear in npj Quantum Materials in 2024. The data were collected while measuring resistivity in high magnetic fields and under applied pressure for a novel iron-based superconductor, FeSe1-xSx (x~0.18). Most of the data are ASCII files related to the figures provided (often (x,y) format).

Abstract:

The upper critical field of multi-band superconductors can be an essential quantity to unravel the nature of superconducting pairing and its interplay with the electronic structure. Here we experimentally map out the complete upper critical field phase diagram of FeSe for different magnetic field orientations at temperatures down to 0.3 K using both resistivity and torque measurements. The temperature dependence of the upper critical field reflects that of a multi-band superconductor and requires a two-band description in the clean limit with band coupling parameters favouring interband over intraband interactions. Despite the relatively small Maki parameter in FeSe of α ∼ 1.6, the multi-band description of the upper critical field is consistent with the stabilization of a FFLO state below T /Tc ∼ 0.3. We find that the anomalous behaviour of the upper critical field is linked to a departure from the single-band picture, and FeSe provides a clear example where multi-band effects and the strong anisotropy of the superconducting gap need to be taken into account.