Evolution of magneto-orbital order upon B-site electron doping in Na1-xCaxMn7O12 quadruple perovskite manganites
Physical Review Letters American Physical Society
Abstract:
We present the discovery and refinement by neutron powder diffraction of a new magnetic phase in the Na1-xCaxMn7O12 quadruple perovskite phase diagram, which is the incommensurate analogue of the well-known pseudo-CE phase of the simple perovskite manganites. We demonstrate that incommensurate magnetic order arises in quadruple perovskites due to the exchange interactions between A and B sites. Furthermore, by constructing a simple mean field Heisenberg exchange model that generically describes both simple and quadruple perovskite systems, we show that this new magnetic phase unifies a picture of the interplay between charge, magnetic and orbital ordering across a wide range of compounds.Structural and Optical Properties of Cs2AgBiBr6 Double Perovskite
ACS Energy Letters American Chemical Society