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Abstract:

Some oxidized compounds in Martian soils may form through heterogeneous electrochemistry (HEC) stimulated by electrostatic discharge (ESD) during dust storms and dust devils. To test this hypothesis, we conducted medium-strength ESD experiments in a Mars simulation chamber and analyzed the Cl, O, and C isotopic compositions of the resulting chloride, (per)chlorate, and carbonate products. These ESD products exhibit substantial mass-dependent depletions in heavy isotopes: ε 37Cl from -11.3 ‰ to +2.0 ‰, ε 18O from -34.5 ‰ to -12.9 ‰, and ε 13C around -11.4 ‰. These results, when compared with isotopic measurements from recent Mars missions (ESA’s ExoMars Trace Gas Orbiter and the Sample Analysis at Mars (SAM) instrument package aboard NASA’s Curiosity rover) and Martian meteorites, indicate that HEC induced by Martian dust activities can account for a substantial portion of the (per)chlorates and carbonates identified at the surface of Mars.

Abstract:

In Titan’s atmosphere, the chemistry of simple hydrocarbons (e.g., CH4 and C2H2) and nitrogen bearing species (e.g., N2 and CN) represents an important link between molecular species and the ubiquitous organic haze that gives Titan its characteristic orange hue. Here we present a new search for two previously undetected molecules, triacetylene (C6H2) and the gas phase dicyanoacetylene (C4N2), using the Echelon-Cross-Echelle Spectrograph instrument on board the Stratospheric Observatory for Infrared Astronomy aircraft. We do not detect these two molecules but determine upper limits for their mixing ratios and column abundances. We find the 3σ upper limits on the uniform volume mixing ratio (VMR) above 100 km for C6H2 to be 4.3 × 10−11, which is lower than the photochemical model predictions. This new upper limit suggests that the growth of linear molecules is inhibited. We also put a strict upper limit on the uniform VMR for gas phase C4N2 above 125 km to be 1.0 × 10−10. This upper limit is well below the saturation mixing ratio at this altitude for C4N2 and greatly limits the feasibility of C4N2 forming ice from condensation.

Abstract:

The Mars Atmosphere and Volatile Evolution (MAVEN) spacecraft has detected as many as 1,125 plasma depletion events (PDEs) in the Martian ionosphere from October 2014 to May 2021. PDEs, characterized by significantly reduced plasma density, elevated electron temperatures, and increased electrostatic fluctuations, remain poorly understood in terms of their formation and spatiotemporal characteristics. This study combines MAVEN data with concurrent observations from Mars Express (MEX) to investigate these aspects. The analysis of PDE recurrence rates across subsequent MAVEN orbits reveals 80 recurring events. These events are formed at the same locations within 18–30 hr. Additionally, we identified two conjugate PDEs observed by both MAVEN and MEX. These observations suggest that PDEs can extend spatially up to 750 km and last for a couple of hours. Our findings suggest that PDEs are large-scale and possibly recurring phenomena, potentially important for ion loss, and that understanding them is important for accurately characterizing the Martian ionosphere.

Abstract:

Plain Language Summary: Earth absorbs energy emitted by the Sun, radiating some of that as heat back into space. The energy exchange between Earth and space drives weather and climate. Scientists measure and track this energy using satellite instruments that can identify which parts of Earth's surface and atmosphere emit specific portions of the overall heat radiated into space. But these instruments are complicated and expensive, and until now, no one has built a sensor that can look at and separate all of Earth's heat emissions in a systematic way. The Polar Radiant Energy in the Far‐InfraRed Experiment (PREFIRE) has developed a novel instrument that combines simple, miniaturized heat sensors with specially shaped optics and microelectronics to provide such measurements to further our understanding of the planet's weather and climate. Furthermore, implementation of the sensors has been done within a cost‐capped mission profile that encourages development of a sustainable sensor system for Earth monitoring. This manuscript describes the instrument design, including its components and their characteristics, the system and its functionality, its trade‐offs, cost limitations, and testing and performance information. PREFIRE began operating two of these instruments in space in 2024, in order to start quantifying the heat exchange processes in Earth's polar regions.