Photochemical modelling of atmospheric oxygen levels confirms two stable states

Earth and Planetary Science Letters Elsevier 561 (2021) 116818

Authors:

Bethan S Gregory, Mark W Claire, Sarah Rugheimer

Abstract:

Various proxies and numerical models have been used to constrain O2 levels over geological time, but considerable uncertainty remains. Previous investigations using 1-D photochemical models have predicted how O3 concentrations vary with assumed ground-level O2 concentrations, and indicate how the ozone layer might have developed over Earth history. These classic models have utilised the numerical simplification of fixed mixing ratio boundary conditions. Critically, this modelling assumption requires verification that predicted fluxes of biogenic and volcanic gases are realistic, but also that the resulting steady states are in fact stable equilibrium solutions against trivial changes in flux.

Here, we use a 1-D photochemical model with fixed flux boundary conditions to simulate the effects on O3 and O2 concentrations as O2 (and CH4) fluxes are systematically varied. Our results suggest that stable equilibrium solutions exist for trace- and high-O2/O3 cases, separated by a region of instability. In particular, the model produces few stable solutions with ground O2 mixing ratios between 6×10−7 and 2×10−3 (3×10−6 and 1% of present atmospheric levels). A fully UV-shielding ozone layer only exists in the high-O2 states. Our atmospheric modelling 91探花s prior work suggesting a rapid bimodal transition between reducing and oxidising conditions and proposes Proterozoic oxygen levels higher than some recent proxies suggest. We show that the boundary conditions of photochemical models matter, and should be chosen and explained with care.

Agriculture's contribution to climate change and role in mitigation is distinct from predominantly fossil CO2-emitting sectors

Frontiers in Sustainable Food Systems Frontiers Media 4 (2021) 518039

Authors:

John Lynch, Michelle Cain, David Frame, Raymond Pierrehumbert

Abstract:

Agriculture is a significant contributor to anthropogenic global warming, and reducing agricultural emissions鈥攍argely methane and nitrous oxide鈥攃ould play a significant role in climate change mitigation. However, there are important differences between carbon dioxide (CO2), which is a stock pollutant, and methane (CH4), which is predominantly a flow pollutant. These dynamics mean that conventional reporting of aggregated CO2-equivalent emission rates is highly ambiguous and does not straightforwardly reflect historical or anticipated contributions to global temperature change. As a result, the roles and responsibilities of different sectors emitting different gases are similarly obscured by the common means of communicating emission reduction scenarios using CO2-equivalence. We argue for a shift in how we report agricultural greenhouse gas emissions and think about their mitigation to better reflect the distinct roles of different greenhouse gases. Policy-makers, stakeholders, and society at large should also be reminded that the role of agriculture in climate mitigation is a much broader topic than climate science alone can inform, including considerations of economic and technical feasibility, preferences for food supply and land-use, and notions of fairness and justice. A more nuanced perspective on the impacts of different emissions could aid these conversations.

Vertically resolved magma ocean鈥損rotoatmosphere evolution: H2 , H2O, CO2, CH4, CO, O2, and N2 as primary absorbers

Journal of Geophysical Research: Planets American Geophysical Union 126:2 (2021) e2020JE006711

Authors:

Tim Lichtenberg, Dan J Bower, Mark Hammond, Ryan Boukrouche, Patrick Sanan, Shang鈥怣in Tsai, Raymond T Pierrehumbert

Abstract:

The earliest atmospheres of rocky planets originate from extensive volatile release during magma ocean epochs that occur during assembly of the planet. These establish the initial distribution of the major volatile elements between different chemical reservoirs that subsequently evolve via geological cycles. Current theoretical techniques are limited in exploring the anticipated range of compositional and thermal scenarios of early planetary evolution, even though these are of prime importance to aid astronomical inferences on the environmental context and geological history of extrasolar planets. Here, we present a coupled numerical framework that links an evolutionary, vertically鈥恟esolved model of the planetary silicate mantle with a radiative鈥恈onvective model of the atmosphere. Using this method we investigate the early evolution of idealized Earth鈥恠ized rocky planets with end鈥恗ember, clear鈥恠ky atmospheres dominated by either H2, H2O, CO2, CH4, CO, O2, or N2. We find central metrics of early planetary evolution, such as energy gradient, sequence of mantle solidification, surface pressure, or vertical stratification of the atmosphere, to be intimately controlled by the dominant volatile and outgassing history of the planet. Thermal sequences fall into three general classes with increasing cooling timescale: CO, N2, and O2 with minimal effect, H2O, CO2, and CH4 with intermediate influence, and H2 with several orders of magnitude increase in solidification time and atmosphere vertical stratification. Our numerical experiments exemplify the capabilities of the presented modeling framework and link the interior and atmospheric evolution of rocky exoplanets with multi鈥恮avelength astronomical observations.

Vertically resolved magma ocean鈥損rotoatmosphere evolution: H2, H2O, CO2, CH4, CO, O2, and N2 as primary absorbers

Journal of Geophysical Research: Planets American Geophysical Union (AGU) (2021)

Authors:

Tim Lichtenberg, Dan J Bower, Mark Hammond, Ryan Boukrouche, Patrick Sanan, Shang鈥怣in Tsai, Raymond T Pierrehumbert

Bifurcation of planetary building blocks during Solar System formation.

Science (New York, N.Y.) 371:6527 (2021) 365-370

Authors:

Tim Lichtenberg, Joanna Drazkowska, Maria Sch枚nb盲chler, Gregor J Golabek, Thomas O Hands

Abstract:

Geochemical and astronomical evidence demonstrates that planet formation occurred in two spatially and temporally separated reservoirs. The origin of this dichotomy is unknown. We use numerical models to investigate how the evolution of the solar protoplanetary disk influenced the timing of protoplanet formation and their internal evolution. Migration of the water snow line can generate two distinct bursts of planetesimal formation that sample different source regions. These reservoirs evolve in divergent geophysical modes and develop distinct volatile contents, consistent with constraints from accretion chronology, thermochemistry, and the mass divergence of inner and outer Solar System. Our simulations suggest that the compositional fractionation and isotopic dichotomy of the Solar System was initiated by the interplay between disk dynamics, heterogeneous accretion, and internal evolution of forming protoplanets.