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Abstract:

Molecular piezoelectrics are a potentially disruptive technology, enabling a new generation of self-powered electronics that are flexible, high performing, and inherently low in toxicity. Although significant efforts have been made toward understanding their structural design by targeted manipulation of phase transition behavior, the resulting achievable piezoresponse has remained limited. In this work, we use a low-symmetry, zero-dimensional (0D) inorganic framework alongside a carefully selected ‘quasi-spherical’ organic cation to manipulate organic–inorganic interactions and thus form the hybrid, piezoelectric material [(CH3)3NCH2I]3Bi2I9. Using variable–temperature single crystal X-ray diffraction and solid-state nuclear magnetic resonance spectroscopy, we demonstrate that this material simultaneously exhibits an order–disorder and displacive symmetry-breaking phase transition. This phase transition is mediated by halogen bonding between the organic and inorganic frameworks and results in a large piezoelectric response, d 33 = 161.5 pm/V. This value represents a 4-fold improvement on previously reported halobismuthate piezoelectrics and is comparable to those of commercial inorganic piezoelectrics, thus offering a new pathway toward low-cost, low-toxicity mechanical energy harvesting and actuating devices.

Abstract:

Perovskite solar cells represent a promising technology in the photovoltaic industry due to their high power conversion efficiency, potential for cost-effective manufacturing and versatile applications. The most stable and efficient perovskites to date rely on lead (Pb), raising concerns about leaching into the environment; however Pb release so far has only been quantified under laboratory conditions, and no field-based assessment under real outdoor expsosure has yet evaluated this risk. The present study quantified Pb leaching from various metal-halide perovskite compositions, device stacks and encapsulation approaches in a rooftop installation for up to 9 months. Pb leaching was low across all tested configurations, even in intentionally damaged materials. Glass–glass encapsulated tandem devices shattered by hail and plastic-encapsulated samples damaged by 100 µm pinholes released only 0.07% ± 0.01% and 0.15% ± 0.14% of their initial Pb, respectively, likely due to the slow diffusion of Pb cations in water. The highest leaching (4.81% ± 0.02%) occurred in unlaminated laboratory devices, demonstrating the importance of proper lamination. A self-developed freeware web tool was used to calculate predicted soil concentrations and evaluate potential impacts. Even for unlaminated devices, concentrations would only slightly exceed natural background levels (5.6 mg kg−1 increase), with negligible effects on soil fertility. A hypothetical worst-case scenario assuming a 1000 nm thick perovskite layer and complete Pb leaching onto a narrow strip of soil predicted a negative impact on soil fertility; however remediation would still not be required under Swiss environmental regulations. Overall, current industry-standard encapsulation limits Pb leaching to levels that almost completely mitigate negative impacts on soil health.

Abstract:

<jats:p>This study pioneers a solvent-additive cascade strategy to achieve crystallographically homogenous perovskite films, breaking the efficiency–stability trade-off by harnessing facet-dependent properties for record performance.</jats:p>

Abstract:

Semi-transparent perovskite solar cells (ST-PSCs) have shown great potential in building-integrated photovoltaics. However, the performance of ST-PSCs is still far from achieving their true potential. Herein, a functional additive, [4-(trifluoromethyl)phenyl] sulfonyl chloride (TFBSC), is incorporated into the perovskite precursor solution to regulate the crystallization process and reduce defects in the perovskite films. The addition of TFBSC improves the perovskite film morphology and increases the charge carrier lifetime and photoluminescence quantum efficiency, compared with the control perovskite films. As a result, the champion device modified with TFBSC shows a power conversion efficiency (PCE) of 14.75% with a light utilization efficiency (LUE) of 3.92%, whereas the control device shows PCE and LUE values of 10.71% and 2.96%, respectively. Moreover, the unencapsulated TFBSC-modified device retains ∼90% of its initial PCE after 1500 h of storage under ambient conditions (relative humidity of ∼30%–40%). These findings could provide new avenues to develop high performance ST-PSCs for smart building applications.