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Abstract:

Whether a planet's volcanic gas is oxidising or reducing is inherited from redox conditions in the planet's mantle. It is often presumed that reactions between iron species control mantle oxygen fugacity. However, iron alone need not be the sole dictator of how oxidising the interior of a planet is. Carbon is a powerful redox element, with great potential to feed back upon the mantle redox state as it melts. Despite Earth being carbon-poor, it has been proposed that the oxygen fugacity of Earth's upper mantle is in part controlled by carbon (Holloway et al., 1992; Stagno et al., 2013); a slightly-higher volatile endowment could make carbon-powered geochemistry inescapable. Indeed, a number of known rocky exoplanets are predicted to have formed with carbon contents greater than Earth (Bergin et al., 2023). We offer a framework for how carbon is transported from solid planetary interior to atmosphere, tracking redox couplings between carbon and iron. We also incorporate a coupled 1D energy- and mass-balance model to provide first-order predictions of the rate of volcanism. We show that carbon-iron redox coupling would maintain interior oxygen fugacity in a narrow range: more reducing than Earth magma, but not reducing enough to prevent CO2 outgassing entirely.Bergin, E. A., Kempton, E. M.-R., Hirschmann, M., Bastelberger, S. T., Teal, D. J., Blake, G. A., Ciesla, F. J., & Li, J. (2023). Exoplanet Volatile Carbon Content as a Natural Pathway for Haze Formation. The Astrophysical Journal, 949, L17. Holloway, J. R., Pan, V., & Gudmundsson, G. (1992). High-pressure fluid-absent melting experiments in the presence of graphite: Oxygen fugacity, ferric/ferrous ratio and dissolved CO2. European Journal of Mineralogy, 4(1), 105–114. Stagno, V., Ojwang, D. O., McCammon, C. A., & Frost, D. J. (2013). The oxidation state of the mantle and the extraction of carbon from Earth’s interior. Nature, 493(7430).

Abstract:

To extract, or 'retrieve' atmospheric properties from the observed radiance spectra from a planetary atmosphere requires software that can generate the expected radiances from a guessed atmospheric model, compare the radiances with those measured, determine how the model should be updated to reduce any discrepancy between the modelled and observed radiances, and then iterate these steps until these differences are minimised. One such retrieval model is NEMESIS (Nonlinear optimal Estimator for MultivariatE Spectral analySIS), which was initially developed by myself and my colleagues in the 1990s, and which has since been continually updated and enhanced. NEMESIS has now been used in more than 300 papers retrieving atmospheric properties from observed thermal and solar-reflected radiance spectra from all the planetary atmospheres in our solar system and also some beyond. NEMESIS uses the Optimal Estimation framework for atmospheric retrievals and is written in FORTRAN. Recently, more Bayesian frameworks have become computationally possible and favoured, especially for exoplanetary retrievals where prior constraints are almost entirely absent. Hence, NEMESIS has recently been updated to Python (ArchNEMESIS), and combined with PyMultiNest to allow nested sampling retrievals that can better explore the degeneracy between different atmospheric properties. I will review how NEMESIS retrievals have improved our understanding of planetary atmospheres over the last 30 years and how the development of ArchNEMESIS has breathed new life into the NEMESIS/ArchNEMESIS project. 

Abstract:

The Lunar-Earth Gravitational Assist (LEGA) of 19-20 August 2024 marked the first in-flight opportunity beyond functional checks to perform MAJIS (Moons and Jupiter Imaging Spectrometer) observations on-board the ESA’s Jupiter Icy Moons Explorer (JUICE) spacecraft. This unique double flyby involved sequential close approaches to the Moon and Earth, offering an unprecedented configuration to evaluate MAJIS under high radiance, rapidly changing geometric, and operationally constrained conditions. A total of 24 hyperspectral image cubes were acquired (5 targeting the Moon and 19 the Earth) providing a dataset of approximately 7.5 Gbit. This work presents the primary goal of this observation campaign, which was to verify key aspects of MAJIS performance, including radiometric and spectral calibration, straylight behavior, geometric alignment, the use of onboard browse products, and interference tests with other JUICE instruments. This event also enabled assessment of thermal behavior and susceptibility to electromagnetic interference, and provided a first operational benchmark for MAJIS and a basis for refining future observation strategies and data analyses during JUICE’s cruise and science phases. In addition, despite limited spatial and temporal coverage of the observations, the analyses presented here and in a series of companion papers of the special issue “The first-ever lunar-Earth flyby: a unique test environment for JUICE” demonstrated the instrument’s ability to characterize mineralogical features on the Moon and atmospheric constituents on Earth. Observations include detection of mafic minerals (some associated to fresh excavated materials), thermal emission, and emissivity variations on the Moon at spatial scale of 100-200 m. Characterization of atmospheric absorption features, thermal brightness, icy cloud properties are captured for the Earth at km-scale and briefly discussed in the framework of the atmospheric biosignatures relevant to exoplanet habitability studies. Near-coincident acquisitions with other JUICE instruments and Earth-orbiting spectrometers provided valuable inter-calibration and cross-validation opportunities.

Abstract:

Abstract Laboratory spectral analysis of well‐characterized meteorite samples can be employed to more quantitatively analyze asteroid remote sensing data in conjunction with returned extraterrestrial samples. In this work, we examine the combined effects of physical (temperature, particle size) and chemical (petrologic type, metal fraction) variables on visible and near‐infrared (VNIR) spectra of ordinary chondrite meteorite powders. Six equilibrated ordinary chondrite meteorite falls were prepared at a variety of particle sizes to capture the spectral diversity associated with asteroid regoliths dominated by various grain sizes. Mineral compositions and abundance were determined from electron microprobe analysis of meteorite thick sections to precisely characterize changes in spectral features due to variations in mineralogy. VNIR spectra of the ordinary chondrites were measured under simulated asteroid surface conditions at a series of temperatures chosen to mimic near‐Earth asteroid surfaces. The resulting spectra show minimal variation in both major absorption bands across the simulated near‐Earth asteroid temperature regime. Changes in particle size result in variations in band centers and band area ratios for material of the same composition, two key parameters typically used to derive asteroid composition. Unlike previous spectral investigations of ordinary chondrites, we retained the metal fraction in our powders instead of analyzing only the silicate fraction. Metal has a subtle but non‐negligible effect on the VNIR spectra of ordinary chondrites. The more petrologically pristine samples from each ordinary chondrite group display relatively weaker absorption bands than their more thermally altered counterparts. The band centers shift to longer wavelengths as grain size and petrologic type increase. Plain Language Summary Remote interpretation of asteroid composition can be complicated by the physical (grain size, temperature) and chemical (mineral composition and abundance) properties of the asteroids themselves. To aid in understanding the effects of these variables and improve our remote interpretation of asteroid compositions from their spectra, we have systematically evaluated the effects of these variables on the visible‐near‐infrared spectra of well‐characterized asteroid samples (e.g., ordinary chondrite meteorites) measured in a simulated asteroid environment. Our results show that while the effect of near‐Earth asteroid temperatures on the spectra appears to be minimal, changes in particle size can mimic changes in spectral band parameters that are typically attributed to composition. It is therefore essential to account for particle size when interpreting composition from silicate‐dominated asteroid spectra. Key Points Near‐Earth asteroid temperatures (∼10–100°C) have a minimal effect on the visible and near‐infrared (VNIR) spectra of olivine and pyroxene dominated ordinary chondrite meteorites Particle size is a critical variable to account for when trying to derive composition from remotely sensed asteroid VNIR spectra Metal content has a subtle but non‐trivial effect on the VNIR spectra of ordinary chondrites

Abstract:

Solar energetic events can have considerable effects on planetary ionospheres. However, the erratic nature of these solar energetic events make observations difficult. Here we show a mutual radio occultation observation, which serendipitously occurred just 10 minutes after a large solar flare impacted Mars. This resulted in the largest lower ionospheric layer ever recorded, where it was 278% its typical size. We used in-situ soft x-ray irradiance measurements to show a threefold increase in flux. This infers a different relation of soft X-ray to this layer's density than previously thought, with variations depending on the amount of spectrum 'hardening' leading to the increase of ionisation from secondaries.