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Abstract:

The Atmospheric Chemistry Suite (ACS) onboard the ExoMars Trace Gas Orbiter (TGO) spacecraft has been studying Mars' atmosphere since 2018. The sensitivity of the middle infrared channel (MIR) allows it to address many ardent topics and it is capable of improving and establishing upper limits for many trace species. In this work we present analysis of transmittance spectra in the 3332.5–3338.6 cm⁻¹ range with 30,000 resolution (λ∕Δλ), covering absorptions lines of three nitrogen-bearing species: ammonia (NH₃), hydrogen cyanide (HCN) and cyanoacetylene (HC₃N). According to existing models, all of those are not expected to be present in a CO₂-rich Martian atmosphere, but outgassing or unknown chemistry sources cannot be discounted. The upper limits of 14, 1.5 and 11 ppbv are obtained for NH₃, HCN and HC₃N from individual occultation measurements during the warm and dusty perihelion season of martian year 36. For the ammonia and hydrogen cyanide the upper limits are improved compared to previously published results. A search for cyanoacetylene on Mars is reported for the first time.

Abstract:

Based on preflight laboratory testing, an unexpectedly large positional offset between the two midinfrared (mid-IR) detector arrays in the Cassini composite infrared spectrometer (CIRS) instrument has been noted in the literature. A much smaller offset was measured in-flight. We investigate this discrepancy by estimating several spatial relationships among the detectors and comparing these results with three independent data sets. This enables us to infer the probable cause of this offset and to derive a new reduced value. We comment on the effect that this change could have on previously published results involving CIRS data. We also present a graphical display of the arrays projected on the sky as CIRS would see it.